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Topic: Synthesis of Alcohols  (Read 2007 times)

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Offline sun725

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Synthesis of Alcohols
« on: April 12, 2017, 03:48:22 PM »
Here are the original questions:
http://imgur.com/a/HGV3D

And here are my answers. I wonder if I've answered them correctly or do I miss anything? If I do, kindly tell me and explain to me.

http://imgur.com/a/LvMEZ

Thanks in advance!
« Last Edit: April 12, 2017, 08:44:20 PM by Arkcon »

Offline AdiDex

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Re: Synthesis of Alcohols
« Reply #1 on: April 14, 2017, 05:00:31 AM »
It seems to be alright.

Offline sun725

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Re: Synthesis of Alcohols
« Reply #2 on: April 14, 2017, 02:10:04 PM »
Are you sure? Cause whenever I type these answers I get it wrong on the program ...

Offline AdiDex

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Re: Synthesis of Alcohols
« Reply #3 on: April 14, 2017, 02:41:24 PM »
Yes 
1st one is a kind of exception to Michael Addition since addition of LiAlH4 undergoes through irreversible pathway, the Kinetically Controlled Product wins out that is 1,2 addition product instead of Michael Addition Product (which is a Thermodynamically Controlled Product)

2nd one is simple addition reaction, what else can be possible? (You can make Its Enolate Form after reaction with R-Li as a minor product, but as soon as you will add Acid, it will revert back in its Keto-Form)

3rd One of the Basic Reduction reaction.
« Last Edit: April 14, 2017, 03:26:21 PM by AdiDex »

Offline sun725

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Re: Synthesis of Alcohols
« Reply #4 on: April 14, 2017, 03:03:40 PM »
Thank you very much. Got them somehow all right now.

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