Hello, I'm coming close to finishing my B.S. in chemistry, and I've been happy to tinker and putter around with chemistry and electronics at home. Nothing fancy, but I find it helpful to "convince myself" of things as I learn about them, and I get a fair amount of benefit in terms of experience with azeotropic and other distillation techniques and old-school separations and identification techniques (modern spectroscopy means it's not something I was ever formally taught.) Electrochemistry is also something I do a fair amount of.
I do like to be very safe: I have a lot of strong acids, bases, and solvents. I store them carefully (separate acids and bases, I keep as little solvent as possible, synthesize ethers only when I need them etc.) I have an ABC fire extinguisher handy. Gloves, goggles, etc. Spray bottles with vinegar and baking soda solutions. I mention all of this in case it helps people understand what the possible issues are.
TL;DR: I'm pretty safe, but I don't have a great eyewash setup. I have two gallon bottles of distilled water in a dedicated area (near the first aid kit) in case I need a deluge or eye wash. I was thinking of buying one of those buffered eyewash kits, but I'm not sure it's an advantage. I work in a finished basement, but I'm pretty far from a sink. I was wondering if people had more advice on the subject.
I may seem a bit overcautious, but honestly, even a small disaster would probably complicate my life a great deal.