The main effect of temperature is to condense the vapour at a different temperature, approximately +119°C at 2bar and +156°C at 6bar. Heat available at +156°C passes more easily in the target fluid than from +119°C, especially if the target temperature is around +100°C.
Depending on exchanger details, the vapour and the liquid may provide heat to the target too, and not only the condensation. Then, the comparison can't rely only on the condensation heat. In fact, the heat of vaporization changes only because when heating water from one temperature to an other, you invest more heat in the liquid and less in the vapour if it boils at a higher temperature, and their heat capacities differ. When the enthalpy of the vapour and the liquid depend little on the pressure (a reasonable assumption at 2bar and 6bar), then bringing the liquid from one given temperature to a vapour at a higher temperature takes the same amount of heat, whatever the pressure.
In your comparison, is it possible that the vapour is saturated in both cases? Then it would also arrive hotter if at 6bar.