November 23, 2024, 06:11:02 AM
Forum Rules: Read This Before Posting


« previous next »
Pages: [1]   Go Down

Topic: Epimerisation of N-sulfinyl imine  (Read 1676 times)

0 Members and 1 Guest are viewing this topic.

Offline mattk92

  • Very New Member
  • *
  • Posts: 1
  • Mole Snacks: +0/-0
Epimerisation of N-sulfinyl imine
« on: February 13, 2018, 04:28:36 PM »
I've got a N-sulfinyl tBu imine and am trying to epimerise the alpha centre. There is a cis-dioxolane at the moment but I'm after the trans. Anyone got any ideas?
I've tried DBU with some success but methoxide, NaHMDS seem to degrade the material
Logged

Offline rolnor

  • Chemist
  • Sr. Member
  • *
  • Posts: 2299
  • Mole Snacks: +154/-10
Re: Epimerisation of N-sulfinyl imine
« Reply #1 on: February 13, 2018, 09:00:44 PM »
Maybe LDA?
Logged
Pages: [1]   Go Up
« previous next »
Sponsored Links