[JuliaLouttit]

Hi all,

I've stumbled on a problem: I'd like to confirm that deuterated solvents should be written with subscript numbers and italicized Ds, when this follows the solvent name (e.g methanol-d₄), but while trying to find a definitive authority on this, I come up blank. I can't find recommendations in IUPAC books etc. Can anyone offer assistance here, even to point to an authoritative source on writing conventions? Thank you in advance! 

[Arkcon]

Although I can be wrong, that particular nomenclature may be archaic, or an older convention, or a localized thing because the printer couldn't handle it any other way.

I have not scoured this particular reference thoroughly, but it seems to me, that IUPAC nomenclature requires identifying the atom, even for deuterium.

ref: http://www.sbcs.qmul.ac.uk/iupac/sectionH/H2.html#2

[sjb]

I've seen it this way, as well as with the d4 label at the start.

Having said that, Fulmer et al, Organometallics, 2010, 29, 2176-9 (doi: 10.1021/om100106e) uses your convention.

[MOTOBALL]

I would follow JACS usage, which presumably is strictly IUPAC.

Regards.

[MOTOBALL]

Quick Google search reveals,

https://pubchem.ncbi.nlm.nih.gov/compound/Methanol-d4

Perdeuteromethanol (Methanol-d4) gives trideuterio(deuteriooxy)methane as IUPAC name.