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Topic: Determine the molar heat of solution of calcium Chloride.  (Read 14422 times)

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Offline Isomer

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Determine the molar heat of solution of calcium Chloride.
« on: July 07, 2006, 08:10:09 PM »
The following data were collected in an experiment designed to determine the molar heat of solution of pure calcium chloride..

mass of calcium chloride.....11.10 g
mass of styrofoam cups.......7.9
mass of water and styrofoam cups.....110.49 g
initial temp of water.......22.7 degrees celsius
highest temp obtained......40.1 degrees celsius

Determine the molar heat of solution of calcium Chloride.

Here is the formula I think I should use...n^H calcium chloride = mc^t styro + mc^t water

Problem is I can't figure out the ^t of the styrofoam, or the ^ H of the calcium chloride. 2 unknowns don't do me any good. Any ideas how to figure out either one?
« Last Edit: July 23, 2006, 03:02:11 AM by geodome »

Offline Isomer

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Or am I being overly confident that I have my formula right?  ???

Offline Yggdrasil

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Since styrofoam is an insulatory material, you would not expect its temperature to change during the experiment.  So, (Delta)T of the styrofoam is essentially zero, which makes your formula a lot easier to deal with.

Offline Isomer

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But wouldn't the styrofoam then take on the temperature of the water? Isn't that what happens in a calorimeter? Logically, I know styrofoam can hold something hot andt be fairly cool, but putting the styrofoam as zero isn't making sense. I don't think at this level of chem my teacher would expect us to know that.

Offline sdekivit

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mass of styrofoam cups.......7.9
mass of water and styrofoam cups.....110.49 g


the only thing you need to know from this data is that you can calculate the mass of water in the calorimeter.

So it's exactly what yggdrasil said ;)

Offline Donaldson Tan

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heat liberated by solvation = heat absorbed by water + heat absorbed by styrofoam cup

heat absorbed by water = mwater.cwater.dTwater
heat absorbed by cup = mcup.ccup.dTcup

given mwater >> mcup and dTwater >> dTcup since styrofoam is an insulator, then heat absorbed by water >> heat absorbed by cup.

Hence, the heat of solvation is approximately equal to the heat absorbed by water corresponding to its temperature increment.
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Offline Isomer

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I found out that there is actually a C value for the styrofoam, so know I have all the proper information to solve this question!

Thanks for the replies.

Offline billnotgatez

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Isomer-

Could you post the C value you used for styrofoam.
Could you post the C value you used for water.

Offline Isomer

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C value for water...4.19

c value for styrofoam.....0.30

Offline billnotgatez

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Thanks

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