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Any combination of volumes and concentrations that yields 1:2 ratio will do, 2M and 1M solutions combined 1:1 look reasonably OK.Beware: FeCl2 is not stable and gets oxidized when stored. Best source of Fe(II) is Mohr's salt.
The second one.But do you need only the ratio 2:1 or do you need 2 M and 1 M in the same solution? If yes think again how to prepare this.