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Topic: High spin vs low spin assignment for Vanadyl (acac)2 complex  (Read 3441 times)

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Offline cyansky

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High spin vs low spin assignment for Vanadyl (acac)2 complex
« on: October 14, 2018, 01:18:57 AM »
I have a question on VO2+ complex. I know that vanadium in VO2+ has +4 oxidation state and it has an unpaired electron in the d-orbital. Based on the notes, they have mentioned that for d4 onwards to d7 has 2 possibilities of arrangement of electrons i.e. high spin and low spin. However, for vanadium in VO2+ only has 1 arrangement since it is d1. It is coordinated with 2 acetylacetone ligands (based on my understanding, it is a weak field ligand), then for the arrangement of electron, does the complex have a high or low spin?

Offline mjc123

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Re: High spin vs low spin assignment for Vanadyl (acac)2 complex
« Reply #1 on: October 15, 2018, 05:22:12 AM »
You've already stated the answer. For a d1 configuration, there is only one possibility.

Offline Traumatic Acid

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Re: High spin vs low spin assignment for Vanadyl (acac)2 complex
« Reply #2 on: October 15, 2018, 09:04:01 PM »
Also, what does the colour of this complex tell you?

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