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Topic: Oxidation States (or multiple valences as my textbook says)  (Read 6067 times)

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Offline Mikez

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Oxidation States (or multiple valences as my textbook says)
« on: August 11, 2006, 01:15:34 PM »
I am having some trouble with this concept and the textbook that I have doesn't explain it (just says to memorize all the possibilities).  How is it possible for oxygen to be -2 and -1?

thanks for your help

Offline tamim83

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Re: Oxidation States (or multiple valences as my textbook says)
« Reply #1 on: August 11, 2006, 02:59:43 PM »
That pretty much means that oxygen can either gain 1 electron (-1) or gain two electrons (-2).  It is just that oxygen anions with a oxidation of -2 is more common. 

Much of the main group elements do not have many common oxidation states.  It is only when you get to transition metals and some lower period main group elements where you have multiple oxidation states.  And yeah, I suppose memorizing the common ones for some (not all, that would really bite) is a good idea.   ;)

Offline sdekivit

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Re: Oxidation States (or multiple valences as my textbook says)
« Reply #2 on: August 11, 2006, 03:13:48 PM »
and peroxides !

Offline tamim83

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Re: Oxidation States (or multiple valences as my textbook says)
« Reply #3 on: August 11, 2006, 03:31:09 PM »
Oooh yeah peroxides.  Oxygen in peroxides have an oxidation state of -1/2. 

Offline Will

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Re: Oxidation States (or multiple valences as my textbook says)
« Reply #4 on: August 11, 2006, 04:55:08 PM »
Oooh yeah peroxides.  Oxygen in peroxides have an oxidation state of -1/2. 

I think oxygen in peroxides have an oxidation state of -1, and in superoxides it is -1/2.

Offline tamim83

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Re: Oxidation States (or multiple valences as my textbook says)
« Reply #5 on: August 12, 2006, 08:28:21 PM »
Yup, you are right will.  :)

Offline Borek

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Re: Oxidation States (or multiple valences as my textbook says)
« Reply #6 on: August 13, 2006, 02:51:53 AM »
I think oxygen in peroxides have an oxidation state of -1, and in superoxides it is -1/2.

Just don't forget it is only for accounting, no real physical meaning :)
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